Original Article
 
The kinetics of eosin yellow removal from aqueous solution using pineapple peels
Fabian Audu Ugbe1, Victoria Abiola Ikudayisi1
Lecturer, Department of Science Laboratory Technology, Benue State Polytechnic, Ugbokolo, Benue State, Nigeria

Article ID: 100006W01FU2017
doi: 10.5348/W01-2017-6-OA-2

Address correspondence to:
Fabian Audu Ugbe
24 Old Otukpo Road, P.0.Box 58
Ugbokolo, Benue State
Nigeria

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How to cite this article
Ugbe FA, Ikudayisi VA. The kinetics of eosin yellow removal from aqueous solution using pineapple peels. Edorium J Waste Manag 2017;2:5–11.

ABSTRACT

Color impurity in industrial effluents constitutes a significant risk to human health and the environment, so much effort has been expended to degrade them using various methods, including the use of agricultural waste materials as adsorbent. The purpose of this study was to provide understanding of the mechanisms for the removal of eosin yellow from aqueous solutions onto pineapple peels as adsorbent. The adsorption equilibrium was studied on effects of initial adsorbate concentration, initial solution pH, and contact time using batch equilibrium techniques. The fitness of equilibrium data to common kinetic models such as pseudo first order, pseudo second order, intraparticle diffusion and film diffusion were tested. From the results obtained for the adsorption experiments, the best adsorption potential was recorded at eosin yellow concentration of 250 mg/L (qe =12.49 mg/g), agitation time of 90 minutes (qe=13.35 mg/g) and initial solution pH of 3 (qe= 22.01 mg/g). Results of kinetic study revealed the order of fittings: Intraparticle diffusion (R2 = 0.981) > Pseudo first order (R2 = 0.978) > Liquid film diffusion (R2 = 0.972) > Pseudo second order (R2 = 0.96). The goodness of fit was observed with the various kinetic models tested, indicating the applicability of these models in the adsorption of eosin yellow on pineapple peels. Thus, the results of the study could provide useful information to evaluate pineapple peels for the practical removal of eosin yellow from aqueous solution.

Keywords:Adsorption, Eosin yellow, Kinetic models, Pineapple peels



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Author Contribution
Fabian Audu Ugbe – Substantial contributions to conception and design, Acquisition of data, Analysis and interpretation of data, Drafting the article, Revising it critically for important intellectual content, Final approval of the version to be published
Victoria Abiola Ikudayisi – Substantial contributions to conception and design, Acquisition of data, Analysis and interpretation of data, Drafting the article, Revising it critically for important intellectual content, Final approval of the version to be published
Guarantor of submission
The corresponding author is the guarantor of submission.
Source of support
None
Conflict of interest
Authors declare no conflict of interest.
Copyright
© 2017 Fabian Audu Ugbe et al. This article is distributed under the terms of Creative Commons Attribution License which permits unrestricted use, distribution and reproduction in any medium provided the original author(s) and original publisher are properly credited. Please see the copyright policy on the journal website for more information.


ABOUT THE AUTHORS

Fabian Audu Ugbe is a Lecturer at the Department of Science Laboratory Technology, Benue State Polytechnic, Ugbokolo, Nigeria. He earned B.Sc. (Chemistry) degree from Bayero University Kano, Nigeria and M.Sc. degree (Chemistry) from University of Ilorin, Nigeria. He has published seven original research papers in national and international academic journals authored two books. Besides, he has two research publications in conference proceedings. His research interests include: Wastewater clean-up of pollutants using adsorption techniques. Metal corrosion inhibition studies using cheap organic, inorganic or green inhibitors.


Victoria Abiola Ikudayisi is a Research Assistant at the Department of Chemistry, University of Ilorin, Nigeria. She earned B.Sc. (Chemistry) degree from Bayero University Kano, Nigeria and M.Sc. (Chemistry) degree from University of Ilorin, Nigeria. She has published five original articles in both national and international academic journals. She has three research publications in conference proceedings and authored a book. Her research interests include: Waste water clean-up of pollutants using adsorption techniques. Metal corrosion inhibition studies using cheap organic, inorganic or green inhibitors.